Reduction in Measurement Time in Electrochemical Impedance Spectroscopy for Efficient Diagnosis of Batteries and Fuel Cells in Dynamic Vehicle Applications

Abstract

This paper presents an innovative approach to modified electrochemical impedance spectroscopy (EIS) for real-time health monitoring of galvanic cells, particularly batteries and fuel cells in high-dynamic applications such as vehicles. Traditional methodologies, including cell voltage monitoring, offer limited diagnostic value. In contrast, conventional EIS provides comprehensive system insights; however, its applicability is constrained by prolonged measurement durations, rendering it impractical for dynamic conditions. This article presents a method that iteratively selects specific frequency bands and key points, thereby substantially reducing measurement time without compromising critical system information. This approach was initially validated using battery systems, which exhibit well-regulated operational behavior, thus facilitating a rigorous evaluation of the concept. Experimental results demonstrated that the modified EIS method achieves performance comparable to conventional EIS but with measurement times reduced by up to 92%. This validation underscores its reliability and precision, thereby supporting proactive maintenance strategies and extending system longevity. The reduction in measurement time enables more precise analyses across diverse dynamic operational spectra. Consequently, this approach constitutes a robust solution for health monitoring of fuel cells and batteries in dynamic environments, capitalizing on the advantages of EIS while addressing its inherent limitations.