Combustion behavior of NMP-001, a nitromethane-based green rocket propellant

Abstract

Hydrazine's carcinogenic and toxic nature makes its use in space propulsion expensive and necessitates careful launch campaign planning, which may cause delays. One already established alternative is to use energetic salt-based ionic solution propellants. However, the costs remain high because these salts are costly and highly regulated energetic materials. Additionally, propellants based on these energetic salts produce much higher temperatures during decomposition and combustion, as is the case for hydrazine. Consequently, expensive refractory metal-based alloys and high-temperature oxidation-resistant catalytic reactors must be used, which further drives up the costs. Alternatively, hydrogen peroxide may be used, though only in applications with a low specific impulse requirement. This study explores a third approach: using nitromethane, a commonly available laboratory solvent. NMP-001 is a nitromethane-based monopropellant that contains additives that allow for low-pressure combustion and reduce sensitivity to mechanical stimuli. Multiple combustion chamber configurations with varying characteristic lengths were tested in rocket combustion experiments. With the 11.5 m L*-configuration, a 15.1 bar low-pressure limit could be determined. The 7.3 and 5.0 m L*-configurations yielded a 16.2 and 28.3 bar low-pressure combustion limits, respectively. These outcomes are significantly below the 30 bar limit reported in the literature. Despite using only a simple heat-sink combustion chamber with a non-sophisticated injector element and a non-optimized propellant formulation, combustion was 83 to 95% efficient with a C* ranged between 1133 to 1302 m/s. These figures are higher than for hydrogen peroxide and are comparable to the theoretical performance state-of-the-art green liquid monopropellants.