Evaluation of the reactivity of dense lanthanum‑gadolinium zirconate ceramics with Colima volcanic ashes

Abstract

The effects of ingestion of airborne particles from pyroclastic events of active volcanoes by aircraft turbines and their subsequent reaction with thermal barrier coatings have attracted the attention of the scientific community in recent years. The reaction products of infiltration experiments of lanthanum‑gadolinium zirconate (LGZO) ceramics with molten ashes from the active Colima volcano at 1250 °C for 10 h are presented and discussed as a function of the Gd3+ content. Five ceramic compositions, varying the Gd3+ content in solid solution were synthesized by the chemical coprecipitation and calcination method of pressed powders. These compositions include pure lanthanum and gadolinium zirconates, LZO, and GZO, respectively. Penetration depth and identification, and in some cases quantification of the reaction products between the molten ash and LGZO ceramics were performed by scanning electron microscopy, chemical composition with energy dispersive X-ray spectroscopy, grazing incident X-ray diffraction as well as micro-Raman spectroscopy. The LZO ceramic exhibited the greatest infiltration resistance with an infiltration depth of approximately 23 μm from the surface. The phase characteristics of the reaction layers were dependent on the gadolinium content. LZO, LGZO25, and LGZO50 (x = 0, 0.25, and 0.5) showed the presence of apatite as well as monoclinic and tetragonal zirconia, while LGZO75 and GZO (x = 0.75 and 1), additionally showed the presence of cubic zirconia and anorthite. As the Gd3+ content increases in the LGZO solid solutions, the wavenumber value corresponding to the stretching vibrational mode of the silicon tetrahedra in apatite shifts from 862 to 877 cm−1, which is associated with a decrease in Sisingle bondO bond lengths. These findings indicate that the amount and kind of rare earth cations dissolved in the melt plays an important role in the precipitation of the reaction products.