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Erosion behavior of CMAS/VA infiltrated EB-PVD Gd2Zr2O7 TBCs: Special emphasis on the effect of mechanical properties of the reaction products

Steinberg, Lars and Mikulla, Christoph and Naraparaju, Ravisankar and Pavlov, Paul and Löffler, Markus and Schulz, Uwe and Leyens, Christoph (2022) Erosion behavior of CMAS/VA infiltrated EB-PVD Gd2Zr2O7 TBCs: Special emphasis on the effect of mechanical properties of the reaction products. WEAR, 506. Elsevier. doi: 10.1016/j.wear.2022.204450. ISSN 0043-1648.

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Abstract

Aero-engines operating in sand-laden (CMAS/CaO-MgO-Al2O3-SiO2) environments often encounter severe problems with thermal barrier coatings (TBCs) due to CMAS infiltration and erosion damage. This study focuses on a deeper understanding of the erosion behavior of CMAS-infiltrated EB-PVD Gd2Zr2O7 TBCs. The study includes isothermal infiltration of different CMAS and subsequent erosion tests at room temperature. In addition to the erosion behavior of the entire coating, the influence of different reaction products within the reaction layer on erosion failure was investigated by measuring the hardness and Young’s modulus of the individual phases using in-situ REM-Nanoindentation. It was found that a garnet layer above the reaction layer and spinel inclusions within a thick apatite/fluorite reaction layer, can improve the erosion resistance of this reaction layer by 30-40%. Furthermore, a correlation between the erosion behavior and the hardness vs. Young’s modulus relation, obtained from nanoindentation over the entire coating, was observed for a consistent microstructure.

Item URL in elib:https://elib.dlr.de/191222/
Document Type:Article
Title:Erosion behavior of CMAS/VA infiltrated EB-PVD Gd2Zr2O7 TBCs: Special emphasis on the effect of mechanical properties of the reaction products
Authors:
AuthorsInstitution or Email of AuthorsAuthor's ORCID iDORCID Put Code
Steinberg, LarsTU dresdenUNSPECIFIEDUNSPECIFIED
Mikulla, ChristophUNSPECIFIEDhttps://orcid.org/0000-0001-9367-8301UNSPECIFIED
Naraparaju, RavisankarUNSPECIFIEDhttps://orcid.org/0000-0002-3944-1132UNSPECIFIED
Pavlov, PaulAnton Paar Germany GMBHUNSPECIFIEDUNSPECIFIED
Löffler, MarkusIWS FraunhoferUNSPECIFIEDUNSPECIFIED
Schulz, UweUNSPECIFIEDhttps://orcid.org/0000-0003-0362-8103UNSPECIFIED
Leyens, ChristophTU Dresden, Fraunhofer-Institut für Werkstoff und Strahltechnik IWSUNSPECIFIEDUNSPECIFIED
Date:12 July 2022
Journal or Publication Title:WEAR
Refereed publication:Yes
Open Access:Yes
Gold Open Access:No
In SCOPUS:Yes
In ISI Web of Science:Yes
Volume:506
DOI:10.1016/j.wear.2022.204450
Publisher:Elsevier
ISSN:0043-1648
Status:Published
Keywords:Gd2Zr2O7; CMAS; TBC, Erosion, EB-PVD
HGF - Research field:Aeronautics, Space and Transport
HGF - Program:Aeronautics
HGF - Program Themes:Clean Propulsion
DLR - Research area:Aeronautics
DLR - Program:L CP - Clean Propulsion
DLR - Research theme (Project):L - Advanced Materials and New Manufacturing Technologies
Location: Köln-Porz
Institutes and Institutions:Institute of Materials Research > High Temperature and Functional Coatings
Deposited By: Naraparaju, Dr Ravisankar
Deposited On:30 Nov 2022 09:05
Last Modified:30 Nov 2022 09:05

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