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Investigating the yield of H2O and H2 from methane oxidation in the stratosphere

Frank, Franziska and Jöckel, Patrick and Gromov, Sergey and Dameris, Martin (2018) Investigating the yield of H2O and H2 from methane oxidation in the stratosphere. Atmospheric Chemistry and Physics (ACP), 18 (13), pp. 9955-9973. Copernicus Publications. DOI: 10.5194/acp-18-9955-2018 ISSN 1680-7316

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Official URL: https://www.atmos-chem-phys.net/18/9955/2018/

Abstract

An important driver of climate change is stratospheric water vapor (SWV), which in turn is influenced by the oxidation of atmospheric methane (CH4). In order to parameterize the production of water vapor (H2O) from CH4 oxidation, it is often assumed that the oxidation of one CH4 molecule yields exactly two molecules of H2O. However, this assumption is based on an early study, which also gives evidence that this is not true at all altitudes. In the current study, we re-evaluate this assumption with a comprehensive systematic analysis using a state-of-the-art chemistry-climate model (CCM), namely the ECHAM/MESSy Atmospheric Chemistry (EMAC) model, and present three approaches to investigate the yield of H2O and hydrogen gas (H2) from CH4 oxidation. We thereby make use of the Module Efficiently Calculating the Chemistry of the Atmosphere (MECCA) in a box model and global model configuration. Furthermore, we use the kinetic chemistry tagging technique (MECCA-TAG) to investigate the chemical pathways between CH4, H2O and H2, by being able to distinguish hydrogen atoms produced by CH4 from H2 from other sources. We apply three approaches, which all agree that assuming a yield of 2 overestimates the production of H2O in the lower stratosphere (calculated as 1.5-1.7). Additionally, transport and subsequent photochemical processing of longer-lived intermediates (mostly H2) raise the local yield values in the upper stratosphere and lower mesosphere above 2 (maximum > 2.2). In the middle and upper mesosphere, the influence of loss and recycling of H2O increases, making it a crucial factor in the parameterization of the yield of H2O from CH4 oxidation. An additional sensitivity study with the Chemistry As A Boxmodel Application (CAABA) shows a dependence of the yield on the hydroxyl radical (OH) abundance. No significant temperature dependence is found. We focus representatively on the tropical zone between 23°S and 23°N. It is found in the global approach that presented results are mostly valid for midlatitudes as well. During the polar night, the method is not applicable. Our conclusions question the use of a constant yield of H2O from CH4 oxidation in climate modeling and encourage to apply comprehensive parameterizations that follow the vertical profiles of the H2O yield derived here and take the chemical H2O loss into account.

Item URL in elib:https://elib.dlr.de/120968/
Document Type:Article
Title:Investigating the yield of H2O and H2 from methane oxidation in the stratosphere
Authors:
AuthorsInstitution or Email of AuthorsAuthors ORCID iD
Frank, FranziskaDLR, IPAhttps://orcid.org/0000-0002-2406-4936
Jöckel, PatrickDLR, IPAhttps://orcid.org/0000-0002-8964-1394
Gromov, SergeyMPI für Chemie, Mainzhttps://orcid.org/0000-0002-2542-3005
Dameris, MartinDLR, IPAUNSPECIFIED
Date:13 July 2018
Journal or Publication Title:Atmospheric Chemistry and Physics (ACP)
Refereed publication:Yes
Open Access:Yes
Gold Open Access:Yes
In SCOPUS:Yes
In ISI Web of Science:Yes
Volume:18
DOI :10.5194/acp-18-9955-2018
Page Range:pp. 9955-9973
Editors:
EditorsEmail
Grooß, Jens-UweFZ Jülich
Publisher:Copernicus Publications
ISSN:1680-7316
Status:Published
Keywords:Methane, stratospheric water vapor, yield
HGF - Research field:Aeronautics, Space and Transport
HGF - Program:Space
HGF - Program Themes:Earth Observation
DLR - Research area:Raumfahrt
DLR - Program:R EO - Erdbeobachtung
DLR - Research theme (Project):R - Project Climatic relevance of atmospheric tracer gases, aerosols and clouds
Location: Oberpfaffenhofen
Institutes and Institutions:Institute of Atmospheric Physics > Earth System Modelling
Deposited By: Frank, Franziska
Deposited On:19 Jul 2018 13:50
Last Modified:02 May 2019 13:59

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