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Source attribution and process analysis for atmospheric mercury in eastern China simulated by CMAQ-Hg

Zhu, J. and Wang, T. and Bieser, J. and Matthias, Volker (2015) Source attribution and process analysis for atmospheric mercury in eastern China simulated by CMAQ-Hg. Atmospheric Chemistry and Physics, 15, pp. 8767-8779. Copernicus Publications. DOI: 10.5194/acp-15-8767-2015 ISSN 1680-7316

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Official URL: http://www.atmos-chem-phys.net/15/8767/2015/

Abstract

The contribution from different emission sources and atmospheric processes to gaseous elemental mercury (GEM), gaseous oxidized mercury (GOM), particulate bound mercury (PBM) and mercury deposition in eastern China were quantified using the Community Multi-scale Air Quality (CMAQ-Hg) modeling system run with a nested domain. Natural sources (NAT) and six categories of anthropogenic mercury sources (ANTH) including cement production (CEM), domestic life (DOM), industrial boilers (IND), metal production (MET), coal-fired power plants (PP) and traffic (TRA) were considered for source apportionment. NAT were responsible for 36.6 % of annual averaged GEM concentration, which was regarded as the most important source for GEM in spite of obvious seasonal variation. Among ANTH, the influence of MET and PP on GEM were most evident especially in winter. ANTH dominated the variations of GOM and PBM concentrations with contributions of 86.7 and 79.1 %, respectively. Among ANTH, IND were the largest contributor for GOM (57.5 %) and PBM (34.4 %) so that most mercury deposition came from IND. The effect of mercury emitted from out of China was indicated by a > 30 % contribution to GEM concentration and wet deposition. The contributions from nine processes – consisting of emissions (EMIS), gas-phase chemical production/loss (CHEM), horizontal advection (HADV), vertical advection (ZADV), horizontal advection (HDIF), vertical diffusion (VDIF), dry deposition (DDEP), cloud processes (CLDS) and aerosol processes (AERO) – were calculated for process analysis with their comparison in urban and non-urban regions of the Yangtze River delta (YRD). EMIS and VDIF affected surface GEM and PBM concentrations most and tended to compensate each other all the time in both urban and non-urban areas. However, DDEP was the most important removal process for GOM with 7.3 and 2.9 ng m−3 reduced in the surface of urban and non-urban areas, respectively, in 1 day. The diurnal profile variation of processes revealed the transportation of GOM from urban area to non-urban areas and the importance of CHEM/AERO in higher altitudes which partly caused diffusion of GOM downwards to non-urban areas. Most of the anthropogenic mercury was transported and diffused away from urban areas by HADV and VDIF and increased mercury concentrations in non-urban areas by HADV. Natural emissions only influenced CHEM and AERO more significantly than anthropogenic. Local emissions in the YRD contributed 8.5 % more to GEM and ~ 30 % more to GOM and PBM in urban areas compared to non-urban areas.

Item URL in elib:https://elib.dlr.de/105755/
Document Type:Article
Title:Source attribution and process analysis for atmospheric mercury in eastern China simulated by CMAQ-Hg
Authors:
AuthorsInstitution or Email of AuthorsAuthors ORCID iD
Zhu, J.School of Atmospheric Sciences, Nanjing University, Nanjing 210093, ChinaUNSPECIFIED
Wang, T.School of Atmospheric Sciences, Nanjing University, Nanjing 210093, ChinaUNSPECIFIED
Bieser, J.DLR, IPAUNSPECIFIED
Matthias, VolkerHelmholtz-Zentrum Geesthacht, GeesthachtUNSPECIFIED
Date:11 August 2015
Journal or Publication Title:Atmospheric Chemistry and Physics
Refereed publication:Yes
Open Access:Yes
Gold Open Access:Yes
In SCOPUS:Yes
In ISI Web of Science:Yes
Volume:15
DOI :10.5194/acp-15-8767-2015
Page Range:pp. 8767-8779
Publisher:Copernicus Publications
ISSN:1680-7316
Status:Published
Keywords:Mercury, Regional modelling
HGF - Research field:Aeronautics, Space and Transport
HGF - Program:Transport
HGF - Program Themes:Transport System
DLR - Research area:Transport
DLR - Program:V VS - Verkehrssystem
DLR - Research theme (Project):V - Verkehrsentwicklung und Umwelt II (old)
Location: Oberpfaffenhofen
Institutes and Institutions:Institute of Atmospheric Physics > Earth System Modelling
Deposited By: Righi, Dr. Mattia
Deposited On:19 Aug 2016 14:54
Last Modified:02 May 2019 14:05

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