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Investigation of Long Term Cycle Stability - First Results of Metal Hydride Composites

Dieterich, Mila and Bürger, Inga and Linder, Marc and Wörner, Antje (2014) Investigation of Long Term Cycle Stability - First Results of Metal Hydride Composites. 14th International Symposium on Metal-Hydrogen Systems, 20.-25.7.2014, Manchaster, UK.

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Abstract

Reversible reactions of solid powders and hydrogen can be used for hydrogen storage as well as for thermal applications like heat storages or heat conversion systems. For all applications, one of the fundamental prerequisites is the cycle stability of the reaction material and - if required - its bulk structure. At the Institute of Technical Thermodynamics at the German Aerospace Center a test bench to investigate the cycle stability of reversible gas/solid-reactions has been developed and brought into operation (Figure 1, left). The main feature is the possibility to investigate larger quantities of the materials and therefore to investigate also complete structures, e.g. matrixes for heat transfer enhancement. Until now Hydralloy C5 pellets have been cycled more than 1000 times. The bench can be operated automatically, provide temperature levels between 50 and 400°C and a pressure up to 100 bar. The temperature is controlled by a thermostatic bath and allows monitoring any shift in the heat transfer during cycling. The pressure can be increased or decreased quickly so highly dynamic tests can be run. The measurement of temperature and pressure is carried out online at different positions and the overall conversion is measured by an included Sievert’s apparatus. In cooperation with the Fraunhofer Institute for Manufacturing Technology and Advanced Materials IFAM we have recently investigated different compositions of hydralloy C5 and graphite as well as four different pellets of metal hydride with different diameter at the same time. Figure 1, right shows the temperature (T), pressure (p) and pressure difference caused by absorption (DSD) for two cycles of one of these pellets as an example.

Item URL in elib:https://elib.dlr.de/93326/
Document Type:Conference or Workshop Item (Poster)
Title:Investigation of Long Term Cycle Stability - First Results of Metal Hydride Composites
Authors:
AuthorsInstitution or Email of AuthorsAuthors ORCID iD
Dieterich, Milamila.dieterich (at) dlr.deUNSPECIFIED
Bürger, Ingainga.buerger (at) dlr.deUNSPECIFIED
Linder, Marcmarc.linder (at) dlr.deUNSPECIFIED
Wörner, Antjeantje.woerner (at) dlr.deUNSPECIFIED
Date:July 2014
Refereed publication:No
Open Access:Yes
Gold Open Access:No
In SCOPUS:No
In ISI Web of Science:No
Status:Published
Keywords:gas/solid reaction, cycle stability, test bench, large qunatities,
Event Title:14th International Symposium on Metal-Hydrogen Systems
Event Location:Manchaster, UK
Event Type:international Conference
Event Dates:20.-25.7.2014
HGF - Research field:Energy
HGF - Program:Efficient Energy Conversion and Use (old)
HGF - Program Themes:Energy-efficient Processes (old)
DLR - Research area:Energy
DLR - Program:E EV - Energy process technology
DLR - Research theme (Project):E - Thermochemical Processes (old)
Location: Stuttgart
Institutes and Institutions:Institute of Engineering Thermodynamics > Thermal Process Technology
Deposited By: Dieterich, Mila
Deposited On:17 Dec 2014 17:42
Last Modified:31 Jul 2019 19:50

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