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CARS investigation of collisional shift of the hydrogen Q-branch transitions by water at high temperatures

Clauss, W. and Oschwald, Michael and Vereschagin, K. A. and Vereschagin, A. K. and Smirnov, V. V. and Fabelinsky, V. I. (2010) CARS investigation of collisional shift of the hydrogen Q-branch transitions by water at high temperatures. Journal of Raman Spectroscopy, Volume 41 (Issue 8), pp. 897-901. Wiley. DOI: DOI: 10.1002/jrs.2697

Full text not available from this repository.

Abstract

A high-resolution (∼0.1 cm−1) spectroscopic method based on the application of a Fabry–Pérot interferometer to the spectral analysis of the coherent anti-Stokes Raman scattering (CARS) signal from an individual Raman transition was used to obtain single-shot spectra of hydrogen Q-branch transitions directly in the flame of a pulsed, high-pressure H2/O2 combustion chamber. Simultaneously with the Fabry–Pérot pattern, a broadband CARS spectrum of the complete H2Q -branch structure was recorded in order to measure the temperature of the probe volume. During every cycle of the combustion chamber, a pressure pulse together with single-shot CARS spectra, providing information on individual line shapes and medium temperature, was recorded. On the basis of the experimental data, the temperature dependences of lineshift coefficients for several Q-branch lines of hydrogen molecules under collisions with water molecules were determined in the temperature range 2100 < T < 3500 K, and an empirical ‘fitting law’ for H2H2O lineshift coefficients is proposed.

Item URL in elib:https://elib.dlr.de/67150/
Document Type:Article
Title:CARS investigation of collisional shift of the hydrogen Q-branch transitions by water at high temperatures
Authors:
AuthorsInstitution or Email of AuthorsAuthors ORCID iD
Clauss, W.Walter.Clauss (at) dlr.deUNSPECIFIED
Oschwald, MichaelMichael.Oschwald (at) dlr.dehttps://orcid.org/0000-0002-9579-9825
Vereschagin, K. A.General Physics Institute, MoscowUNSPECIFIED
Vereschagin, A. K.General Physics Institute, MoscowUNSPECIFIED
Smirnov, V. V.General Physics Institute, MoscowUNSPECIFIED
Fabelinsky, V. I.General Physics Institute, MoscowUNSPECIFIED
Date:August 2010
Journal or Publication Title:Journal of Raman Spectroscopy
Refereed publication:Yes
Open Access:No
Gold Open Access:No
In SCOPUS:Yes
In ISI Web of Science:Yes
Volume:Volume 41
DOI :DOI: 10.1002/jrs.2697
Page Range:pp. 897-901
Publisher:Wiley
Status:Published
Keywords:CARS; spectroscopy; linewidth measurements; collisional shift; Fabry-Pérot interferometry; CARS
HGF - Research field:Aeronautics, Space and Transport (old)
HGF - Program:Space (old)
HGF - Program Themes:W - no assignment
DLR - Research area:Space
DLR - Program:W - no assignment
DLR - Research theme (Project):W - no assignment (old)
Location: Lampoldshausen
Institutes and Institutions:Institute of Space Propulsion > Rocket Propulsion
Deposited By: Hanke, Michaela
Deposited On:06 Dec 2010 17:50
Last Modified:01 Dec 2018 19:47

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