Griesche, A. and Zhang, B. and Horbach, J. and Meyer, A. (2010) Interdiffusion and thermodynamic forces in binary liquid alloys. Materials Science Forum, 649, p. 481. Trans Tech Publications. doi: 10.4028/www.scientific.net/MSF.649.481.
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Abstract
A novel X-ray radiography method is used to measure chemical diffusion in a longcapillary in liquid Al95Ni5 at.-%. Molecular dynamics simulations provide interdiffusion coefficients and thermodynamic factors for the whole composition range in Al-Ni. The data are compared to literature data in Sb-Sn and Ag-Sn. The relation between interdiffusion coefficient and thermodynamic forces is discussed in the context of the Darken equation. In systems with common ordering tendency (Al-Ni, Sb-Sn) the thermodynamic factor is larger than one and enhances interdiffusion. In systems with common demixing tendency (Ag-Sn) the thermodynamic factor is smaller than one and reduces interdiffusion.
Item URL in elib: | https://elib.dlr.de/62958/ | ||||||||||||||||||||
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Document Type: | Article | ||||||||||||||||||||
Title: | Interdiffusion and thermodynamic forces in binary liquid alloys | ||||||||||||||||||||
Authors: |
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Date: | January 2010 | ||||||||||||||||||||
Journal or Publication Title: | Materials Science Forum | ||||||||||||||||||||
Refereed publication: | Yes | ||||||||||||||||||||
Open Access: | No | ||||||||||||||||||||
Gold Open Access: | No | ||||||||||||||||||||
In SCOPUS: | Yes | ||||||||||||||||||||
In ISI Web of Science: | No | ||||||||||||||||||||
Volume: | 649 | ||||||||||||||||||||
DOI: | 10.4028/www.scientific.net/MSF.649.481 | ||||||||||||||||||||
Page Range: | p. 481 | ||||||||||||||||||||
Publisher: | Trans Tech Publications | ||||||||||||||||||||
Status: | Published | ||||||||||||||||||||
Keywords: | Interdiffusion, Self Diffusion, X-ray Radiography, Al-Alloys, Darken Equation | ||||||||||||||||||||
HGF - Research field: | Aeronautics, Space and Transport (old) | ||||||||||||||||||||
HGF - Program: | Space (old) | ||||||||||||||||||||
HGF - Program Themes: | W FR - Forschung unter Weltraumbedingungen (old) | ||||||||||||||||||||
DLR - Research area: | Space | ||||||||||||||||||||
DLR - Program: | W FR - Forschung unter Weltraumbedingungen | ||||||||||||||||||||
DLR - Research theme (Project): | W - Vorhaben Materialwissenschaftliche Forschung (old) | ||||||||||||||||||||
Location: | Köln-Porz | ||||||||||||||||||||
Institutes and Institutions: | Institute of Materials Physics in Space | ||||||||||||||||||||
Deposited By: | Meyer, Prof.Dr. Andreas | ||||||||||||||||||||
Deposited On: | 27 Jan 2010 08:49 | ||||||||||||||||||||
Last Modified: | 14 Mar 2024 15:34 |
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