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Stützer, Robert and Balkenhohl, Jakob and Lauck, Felix and Oschwald, Michael and Schlechtriem, Stefan (2022) Hypergolic Reaction Between the Green Ionic Liquid EMIM SCN and Hydrogen Peroxide in a Lab-Scale Drop Test Chamber. International Journal of Energetic Materials and Chemical Propulsion, 1, pp. 87-100. Begell House. doi: 10.1615/IntJEnergeticMaterialsChemProp.2021038219. ISSN 2150-766X.
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Official URL: https://www.dl.begellhouse.com/journals/17bbb47e377ce023,569acf27247a762c,77fba1f73d959879.html#
Abstract
The hypergolic reaction between the recently developed green propellant combination consisting of an ionic liquid and highly concentrated hydrogen peroxide was investigated for various fuel to oxidizer ratios and heights of fall. The influence of the catalytic copper additive on the ignition delay time (IDT) was analyzed. Flame emission/absorption spectroscopy revealed the chemical constituents. All emission spectra were dominated by the sodium D-lines at a wavelength of lambda = 589 nm. Further lines of alkali metals such as lithium and potassium were found. The copper additive showed its characteristic lines according to its amount in the fuel. Emission spectra of the ultraviolet regime showed the characteristic OH* molecular lines around a wavelength of lambda = 306 nm with its temperature dependent intensity ratios. The catalytic additive copper (I) thio-cyanate (CuSCN) increases the temperature of the OH* molecule in the flame while it decreases the IDT from 31 ms for pure ionic liquid to 15 ms (5% mass percentage).
| Item URL in elib: | https://elib.dlr.de/185925/ | ||||||||||||||||||||||||
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| Document Type: | Article | ||||||||||||||||||||||||
| Title: | Hypergolic Reaction Between the Green Ionic Liquid EMIM SCN and Hydrogen Peroxide in a Lab-Scale Drop Test Chamber | ||||||||||||||||||||||||
| Authors: |
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| Date: | 15 January 2022 | ||||||||||||||||||||||||
| Journal or Publication Title: | International Journal of Energetic Materials and Chemical Propulsion | ||||||||||||||||||||||||
| Refereed publication: | Yes | ||||||||||||||||||||||||
| Open Access: | Yes | ||||||||||||||||||||||||
| Gold Open Access: | No | ||||||||||||||||||||||||
| In SCOPUS: | Yes | ||||||||||||||||||||||||
| In ISI Web of Science: | Yes | ||||||||||||||||||||||||
| Volume: | 1 | ||||||||||||||||||||||||
| DOI: | 10.1615/IntJEnergeticMaterialsChemProp.2021038219 | ||||||||||||||||||||||||
| Page Range: | pp. 87-100 | ||||||||||||||||||||||||
| Publisher: | Begell House | ||||||||||||||||||||||||
| ISSN: | 2150-766X | ||||||||||||||||||||||||
| Status: | Published | ||||||||||||||||||||||||
| Keywords: | Hypergolic Ignition, Combustion, Droplet Test Chamber, Spectroscopy | ||||||||||||||||||||||||
| HGF - Research field: | Aeronautics, Space and Transport | ||||||||||||||||||||||||
| HGF - Program: | Space | ||||||||||||||||||||||||
| HGF - Program Themes: | Space Transportation | ||||||||||||||||||||||||
| DLR - Research area: | Raumfahrt | ||||||||||||||||||||||||
| DLR - Program: | R RP - Space Transportation | ||||||||||||||||||||||||
| DLR - Research theme (Project): | R - Reusable Space Systems and Propulsion Technology | ||||||||||||||||||||||||
| Location: | Lampoldshausen | ||||||||||||||||||||||||
| Institutes and Institutions: | Institute of Space Propulsion Institute of Space Propulsion > Rocket Propulsion Technology Institute of Space Propulsion > Rocket Propulsion Institute of Space Propulsion > Propellants | ||||||||||||||||||||||||
| Deposited By: | Stützer, Dr. Robert | ||||||||||||||||||||||||
| Deposited On: | 30 Mar 2022 07:13 | ||||||||||||||||||||||||
| Last Modified: | 16 Jun 2023 09:24 |
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