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Short-range order in undercooled Co melts

Holland-Moritz, D. and Schenk, T. and Bellissent, R. and Simonet, V. and Funakoshi, K. and Merino, J. M. and Buslaps, T. and Reutzel, S. (2002) Short-range order in undercooled Co melts. Journal of Non-Crystalline Solids, 312/314, pp. 47-51. doi: 10.1016/S0022-3093(02)01648-4.

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It was suggested in 1952 by Frank that an icosahedral short-rangeorder(SRO) should be energetically favourable in undercooled melts of systems consisting of atoms with a sphere-like geometrical symmetry. Although this idea is nearly 50 years old, there is still a lack of direct experimental information on the SRO prevailing in undercooled metallic liquids. In this work the results of investigations of the SRO of deeply undercooled liquids of Co by energydispersive diffraction of synchrotron radiation are presented. The experimentally determined structure factors were simulated by assuming that the liquid consists of clusters with different short-range structures. The best fit of the experimental data is obtained if an icosahedral SRO is assumed. Thus, our investigations strongly support Frank’s idea of an icosahedral SRO prevailing in undercooled metallic liquids.

Item URL in elib:https://elib.dlr.de/15827/
Document Type:Article
Additional Information: LIDO-Berichtsjahr=2002,
Title:Short-range order in undercooled Co melts
AuthorsInstitution or Email of AuthorsAuthor's ORCID iD
Bellissent, R.Centre d'Etudes Nucléaires de Grenoble, Grenoble/FUNSPECIFIED
Simonet, V.Universität Paris-Süd/FUNSPECIFIED
Funakoshi, K.Japan Synchrotron Radiation Facility, Sayo/JapanUNSPECIFIED
Merino, J. M.European Synchrotron Facility, Grenoble/FUNSPECIFIED
Buslaps, T.European Synchrotron Facility, Grenoble/FUNSPECIFIED
Journal or Publication Title:Journal of Non-Crystalline Solids
Refereed publication:Yes
Open Access:No
Gold Open Access:No
In ISI Web of Science:Yes
DOI :10.1016/S0022-3093(02)01648-4
Page Range:pp. 47-51
Keywords:Unterkühlung von Materialien
HGF - Research field:Aeronautics, Space and Transport (old)
HGF - Program:Space (old)
HGF - Program Themes:W FR - Forschung unter Weltraumbedingungen (old)
DLR - Research area:Space
DLR - Program:W FR - Forschung unter Weltraumbedingungen
DLR - Research theme (Project):W - Vorhaben Materialwissenschaftliche Forschung (old)
Location: Köln-Porz
Institutes and Institutions:Institute of Materials Physics in Space > Institute of Space Simulation > Center for Solidification of Undercooled Melts (ZEUS)
Deposited By: DLR-Beauftragter, elib
Deposited On:31 Jul 2006
Last Modified:14 Jan 2010 14:44

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