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Integration assessment of the hybrid sulphur cycle with a copper production plant

Seyfaee, Achmad and Jafarian, Mehdi and Moumin, Gkiokchan and Thomey, Dennis and Corgnale, Claudio and Sattler, Christian (2021) Integration assessment of the hybrid sulphur cycle with a copper production plant. Energy Conversion and Management, 249, p. 114832. Elsevier. doi: 10.1016/j.enconman.2021.114832. ISSN 0196-8904.

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Official URL: https://www.sciencedirect.com/science/article/pii/S0196890421010086?via%3Dihub

Abstract

Copper is the third-most widely-used metal worldwide. However, copper processing is an energy-intensive process consuming large quantities of fossil fuels, both as the reducing agent and for energy which contributes significantly to anthropogenic carbon dioxide emissions. The hybrid sulphur cycle combines concentrating solar thermal energy with electrolysis to offer strong potential for low-cost green hydrogen production. A preliminary evaluation is reported of the techno-economic potential of this cycle to displace current fossil-based energy sources in an integrated copper mine and refinery (cradle-to-gate approach) at a remote location in Australia with an excellent solar resource. The effect of ore composition on the integration of the hybrid sulphur cycle and copper processing plant is evaluated using models developed in Aspen Plus. The evaluations show that sizing the hybrid sulphur cycle cycle to meet the oxygen demand of the copper refining process is more technoeconomically viable than sizing the hybrid sulphur cycle to meet the hydrogen required to replace the fossil fuel demand of the copper processing process. Moreover, it has been found that the integration of the hybrid sulphur cycle with the copper process plant has the potential to decrease both the carbon dixoide emissions and the operational expenditure of copper refineries for ores with a sufficiently high sulphide content (~50% mass fraction).

Item URL in elib:https://elib.dlr.de/145992/
Document Type:Article
Title:Integration assessment of the hybrid sulphur cycle with a copper production plant
Authors:
AuthorsInstitution or Email of AuthorsAuthor's ORCID iDORCID Put Code
Seyfaee, AchmadUniv. of AdelaideUNSPECIFIEDUNSPECIFIED
Jafarian, MehdiUniv. of AdelaideUNSPECIFIEDUNSPECIFIED
Moumin, GkiokchanUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Thomey, DennisUNSPECIFIEDhttps://orcid.org/0000-0001-6936-3350UNSPECIFIED
Corgnale, ClaudioGreenway EnergyUNSPECIFIEDUNSPECIFIED
Sattler, ChristianUNSPECIFIEDhttps://orcid.org/0000-0002-4314-1124UNSPECIFIED
Date:23 October 2021
Journal or Publication Title:Energy Conversion and Management
Refereed publication:Yes
Open Access:Yes
Gold Open Access:No
In SCOPUS:Yes
In ISI Web of Science:Yes
Volume:249
DOI:10.1016/j.enconman.2021.114832
Page Range:p. 114832
Publisher:Elsevier
ISSN:0196-8904
Status:Published
Keywords:Hydrogen production Sulphur cycle Copper Solar energy Carbon dioxide emissions
HGF - Research field:Energy
HGF - Program:Materials and Technologies for the Energy Transition
HGF - Program Themes:Chemical Energy Carriers
DLR - Research area:Energy
DLR - Program:E SW - Solar and Wind Energy
DLR - Research theme (Project):E - Solar Fuels
Location: Köln-Porz
Institutes and Institutions:Institute of Future Fuels
Institute of Future Fuels > Solar-Chemical Process Development
Deposited By: Bülow, Mark
Deposited On:07 Jan 2022 11:46
Last Modified:28 Jun 2023 13:12

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