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Ionic conductivity of melt-frozen LiBH4 films

Trück, Janina and Hadjixenophontos, Efi and Joshi, Yug and Richter, Gunther and Stender, Patrick and Schmitz, Guido (2019) Ionic conductivity of melt-frozen LiBH4 films. RSC Advances, 9 (66). Royal Society of Chemistry. doi: 10.1039/C9RA06821J. ISSN 2046-2069.

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Official URL: https://pubs.rsc.org/en/content/articlelanding/2019/RA/C9RA06821J#!divAbstract

Abstract

The fast Li conductivity of LiBH4 envisages its use in all-solid-state batteries. Powders are commonly applied. But here, we study the formation of dense micrometer films by melting, spinning and subsequent solidifying. Characterized by electron microscopy, and spectroscopy (EDX/XPS/impedance), a reversible phase transformation is confirmed as well as a maximum conductivity of 103 S cm−1.

Item URL in elib:https://elib.dlr.de/131413/
Document Type:Article
Additional Information:The research leading to these results has received funding from the European Marie Curie Actions under ECOSTORE grant agreement no 607040
Title:Ionic conductivity of melt-frozen LiBH4 films
Authors:
AuthorsInstitution or Email of AuthorsAuthor's ORCID iDORCID Put Code
Trück, JaninaUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Hadjixenophontos, EfiEfi.Hadjixenophontos (at) dlr.deUNSPECIFIEDUNSPECIFIED
Joshi, YugUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Richter, GuntherUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Stender, PatrickUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Schmitz, GuidoUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Date:November 2019
Journal or Publication Title:RSC Advances
Refereed publication:Yes
Open Access:Yes
Gold Open Access:Yes
In SCOPUS:Yes
In ISI Web of Science:Yes
Volume:9
DOI:10.1039/C9RA06821J
Publisher:Royal Society of Chemistry
ISSN:2046-2069
Status:Published
Keywords:LiBH4, solid state electrolyte, molten films, ionic conduction
HGF - Research field:Energy
HGF - Program:Storage and Cross-linked Infrastructures
HGF - Program Themes:Electrochemical Energy Storage
DLR - Research area:Energy
DLR - Program:E SP - Energy Storage
DLR - Research theme (Project):E - Electrochemical Prcesses (Batteries) (old), E - Materials for Energy Technologies (old)
Location: Stuttgart
Institutes and Institutions:Institute of Engineering Thermodynamics > Electrochemical Energy Technology
Deposited By: Hadjixenophontos, Efi
Deposited On:19 Dec 2019 15:31
Last Modified:19 Dec 2019 15:31

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