Häcker, Joachim and Danner, Christian and Zhao-Karger, Zhirong and Sievert, Brigitta / BS and Wagner, Norbert and Friedrich, K. Andreas (2018) Investigation of Magnesium-Sulfur Batteries using Electrochemical Impedance Spectroscopy. 2nd International Symposium on Magnesium Batteries, 2018-09-27 - 2018-09-28, Deutschland, Ulm.
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Abstract
The combination of magnesium and sulfur in an electrochemical cell is a promising candidate to cope the need of high-energy batteries for future applications like electric vehicles. Due to the abundance and non-toxicity of both elements it is not only a low cost and environmentally friendly couple but also ensures safety as magnesium offers dendrite-free deposition. Theoretically, a cell voltage of 1.77 V and an energy density of 3200 Wh l-1 can be achieved. However, the Mg-S system suffers from fast capacity decay in the first cycles and poor cycle life. Nevertheless, significant research progress is gained since the first report by Kim et al. in 2011 [1], especially in the development of suitable electrolytes. Recently, Zhao-Karger et al. synthesized a chloride-free Mg(BH4)2-derived electrolyte [2] with enhanced properties in terms of electrochemical and thermal stability as well as cycling performance. Still, despite sophisticated studies the mechanisms leading to fast cell degradation are not well understood. To identify intrinsic processes electrochemical impedance spectroscopy (EIS) was applied to Mg-S cells as a function of open cell voltage (OCV), state of charge (SOC) and temperature. As the occurring reactions are difficult to be separated also symmetrical cells were examined by the means of the distribution of relaxation times (DRT). From these insights an electric equivalent circuit based on R-CPE circuits was developed in which each circuit is assigned to a specific intrinsic process. Overall, these results indicate that the magnesium electrode features surfaces layers, which cause overpotentials and limited cycle life. In addition, the retention of polysulfides in the sulfur electrode is crucial as they not only cause loss of active material but also are incorporated in forming passivating layers on the magnesium anode.
Item URL in elib: | https://elib.dlr.de/122831/ | ||||||||||||||||||||||||||||
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Document Type: | Conference or Workshop Item (Speech) | ||||||||||||||||||||||||||||
Title: | Investigation of Magnesium-Sulfur Batteries using Electrochemical Impedance Spectroscopy | ||||||||||||||||||||||||||||
Authors: |
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Date: | 28 September 2018 | ||||||||||||||||||||||||||||
Refereed publication: | No | ||||||||||||||||||||||||||||
Open Access: | No | ||||||||||||||||||||||||||||
Gold Open Access: | No | ||||||||||||||||||||||||||||
In SCOPUS: | No | ||||||||||||||||||||||||||||
In ISI Web of Science: | No | ||||||||||||||||||||||||||||
Status: | Published | ||||||||||||||||||||||||||||
Keywords: | Magnesium-Sulfur Battery, Magnesium-Schwefel Batterie, Magnesium, Elektrochemische Impedanzspektroskopie, EIS | ||||||||||||||||||||||||||||
Event Title: | 2nd International Symposium on Magnesium Batteries | ||||||||||||||||||||||||||||
Event Location: | Deutschland, Ulm | ||||||||||||||||||||||||||||
Event Type: | international Conference | ||||||||||||||||||||||||||||
Event Start Date: | 27 September 2018 | ||||||||||||||||||||||||||||
Event End Date: | 28 September 2018 | ||||||||||||||||||||||||||||
HGF - Research field: | Energy | ||||||||||||||||||||||||||||
HGF - Program: | Storage and Cross-linked Infrastructures | ||||||||||||||||||||||||||||
HGF - Program Themes: | Electrochemical Energy Storage | ||||||||||||||||||||||||||||
DLR - Research area: | Energy | ||||||||||||||||||||||||||||
DLR - Program: | E SP - Energy Storage | ||||||||||||||||||||||||||||
DLR - Research theme (Project): | E - Electrochemical Prcesses (Batteries) (old) | ||||||||||||||||||||||||||||
Location: | Stuttgart | ||||||||||||||||||||||||||||
Institutes and Institutions: | Institute of Engineering Thermodynamics > Electrochemical Energy Technology | ||||||||||||||||||||||||||||
Deposited By: | Häcker, Joachim | ||||||||||||||||||||||||||||
Deposited On: | 19 Nov 2018 15:59 | ||||||||||||||||||||||||||||
Last Modified: | 24 Apr 2024 20:26 |
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