Versenden
Drucken
Otero, Manuel und Heim, Christopher und Leiva, Ezequiel und Wagner, Norbert und Friedrich, Kaspar Andreas (2018) Design-Considerations regarding Silicon/Graphite and Tin/Graphite Composite Electrodes for Lithium-Ion Batteries. Scientific Reports, 8 (1). Nature Publishing Group. doi: 10.1038/s41598-018-33405-y. ISSN 2045-2322.
![[img]](https://elib.dlr.de/style/images/fileicons/application_pdf.png) |
PDF
2MB |
Offizielle URL: http://www.nature.com/articles/s41598-018-33405-y
Kurzfassung
An analytical model is proposed to investigate properties of composite electrodes that utilize more than one active material. We demonstrate how the equations can be applied to aid in the design of electrodes by comparing silicon-graphite and tin-graphite composite negative electrodes as examples with practical relevance. Based on simple assumptions, the results show how volume expansion tolerance and initial porosity are important factors for the achievable gravimetric and volumetric capacities as well as volumetric energy density. A Si-alloy/graphite composite electrode is used as an experimental system to corroborate the formulated analysis. Kinetic limitations are also addressed based on a novel heuristic approach.
| elib-URL des Eintrags: | https://elib.dlr.de/122811/ | ||||||||||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Dokumentart: | Zeitschriftenbeitrag | ||||||||||||||||||||||||
| Zusätzliche Informationen: | Publikation in Kooperation mit der Universität Cordoba, Argentinien. | ||||||||||||||||||||||||
| Titel: | Design-Considerations regarding Silicon/Graphite and Tin/Graphite Composite Electrodes for Lithium-Ion Batteries | ||||||||||||||||||||||||
| Autoren: |
| ||||||||||||||||||||||||
| Datum: | 26 Oktober 2018 | ||||||||||||||||||||||||
| Erschienen in: | Scientific Reports | ||||||||||||||||||||||||
| Referierte Publikation: | Ja | ||||||||||||||||||||||||
| Open Access: | Ja | ||||||||||||||||||||||||
| Gold Open Access: | Ja | ||||||||||||||||||||||||
| In SCOPUS: | Ja | ||||||||||||||||||||||||
| In ISI Web of Science: | Ja | ||||||||||||||||||||||||
| Band: | 8 | ||||||||||||||||||||||||
| DOI: | 10.1038/s41598-018-33405-y | ||||||||||||||||||||||||
| Verlag: | Nature Publishing Group | ||||||||||||||||||||||||
| Name der Reihe: | Nature Scientific Reports | ||||||||||||||||||||||||
| ISSN: | 2045-2322 | ||||||||||||||||||||||||
| Status: | veröffentlicht | ||||||||||||||||||||||||
| Stichwörter: | Battery, Model, Silicon, Electrode, Li-Ion | ||||||||||||||||||||||||
| HGF - Forschungsbereich: | Energie | ||||||||||||||||||||||||
| HGF - Programm: | Speicher und vernetzte Infrastrukturen | ||||||||||||||||||||||||
| HGF - Programmthema: | Elektrochemische Energiespeicher | ||||||||||||||||||||||||
| DLR - Schwerpunkt: | Energie | ||||||||||||||||||||||||
| DLR - Forschungsgebiet: | E SP - Energiespeicher | ||||||||||||||||||||||||
| DLR - Teilgebiet (Projekt, Vorhaben): | E - Elektrochemische Prozesse (Batterien) (alt) | ||||||||||||||||||||||||
| Standort: | Stuttgart | ||||||||||||||||||||||||
| Institute & Einrichtungen: | Institut für Technische Thermodynamik > Elektrochemische Energietechnik | ||||||||||||||||||||||||
| Hinterlegt von: | Heim, Christopher | ||||||||||||||||||||||||
| Hinterlegt am: | 04 Dez 2018 16:05 | ||||||||||||||||||||||||
| Letzte Änderung: | 04 Dez 2018 16:05 |
Nur für Mitarbeiter des Archivs: Kontrollseite des Eintrags
