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Analysis of the nu8 and nu8 + nu9 band spectral regions of BrONO2 and first determination of the nu9 band center at 111.9(7) cm-1

Orphal, J. and Birk, Manfred and Wagner, Georg and Flaud, Jean-Marie (2017) Analysis of the nu8 and nu8 + nu9 band spectral regions of BrONO2 and first determination of the nu9 band center at 111.9(7) cm-1. Chemical Physics Letters, 690, pp. 82-85. Elsevier. DOI: 10.1016/j.cplett.2017.10.031 ISSN 0009-2614

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Abstract

The m8 band region of BrONO2 around 14 mm has been studied at high resolution. The band structure is highly similar to the nu8 band of ClONO2: in addition to very regular Q branches at the low energy side of the band and the main nu8 Q branch located at 722.4 cm-1, a second Q branch is visible at 723.9 cm-1. When attributing this peak to the nu8+nu9 - nu9 band center (as in ClONO2), together with a very weak band observed at 835.8 cm-1, one can determine the nu9 band center to be 111.9 (7) cm-1, in agreement with ab initio calculations.

Item URL in elib:https://elib.dlr.de/117026/
Document Type:Article
Title:Analysis of the nu8 and nu8 + nu9 band spectral regions of BrONO2 and first determination of the nu9 band center at 111.9(7) cm-1
Authors:
AuthorsInstitution or Email of AuthorsAuthors ORCID iD
Orphal, J.Karlsruhe Institute of Technology, Institute for Meteorology and Climate Research, Eggenstein-Leopoldshafen 76344, GERMANYUNSPECIFIED
Birk, Manfredmanfred.birk (at) dlr.deUNSPECIFIED
Wagner, GeorgGeorg.Wagner (at) dlr.deUNSPECIFIED
Flaud, Jean-MarieLISA, CNRS and University of Paris-Est, Creteil, FranceUNSPECIFIED
Date:2017
Journal or Publication Title:Chemical Physics Letters
Refereed publication:Yes
Open Access:No
Gold Open Access:No
In SCOPUS:Yes
In ISI Web of Science:Yes
Volume:690
DOI :10.1016/j.cplett.2017.10.031
Page Range:pp. 82-85
Publisher:Elsevier
ISSN:0009-2614
Status:Published
Keywords:bromine nitrate, BrONO2, high resolution, infrared, Fourier-transfom spectroscopy
HGF - Research field:Aeronautics, Space and Transport
HGF - Program:Space
HGF - Program Themes:Earth Observation
DLR - Research area:Raumfahrt
DLR - Program:R EO - Erdbeobachtung
DLR - Research theme (Project):Vorhaben Spectroscopic Methods in Remote Sensing
Location: Oberpfaffenhofen
Institutes and Institutions:Remote Sensing Technology Institute > Experimental Methods
Deposited By: Birk, Manfred
Deposited On:19 Dec 2017 17:48
Last Modified:06 Sep 2019 15:24

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