Cañas, Natalia A. und Fronczek, David Norman und Wagner, Norbert und Latz, Arnulf und Friedrich, K. Andreas (2014) Experimental and Theoretical Analysis of Products and Reaction Intermediates of Discharge Process in Lithium-Sulfur Batteries. 65th Annual Meeting of the International Society of Electrochemistry, 2014-08-31 - 2014-09-05, Lausanne, Schweiz.
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Kurzfassung
The identification and quantification of species involved in the electrochemical reactions of lithium-sulfur batteries are still unclear and controversial aspects of the investigation of these cells. However, a deeper understanding of the system is crucial to improve the capacity and cycling stability of the cell. In this work, the reduction process of sulfur in a lithium-sulfur battery was studied using UV-Vis spectroscopy under argon atmosphere [1]. Absorbance maxima of dissolved sulfur and polysulfide species were determined at various concentrations. Reference solutions of polysulfides reduce the λmax in the UV-region with decrease of polysulfide order. This tendency is also observed between 25–75% depth of discharge due to the progressive reduction of polysulfides in the electrolyte. Because the application of UV-Vis spectroscopy alone does not provide a complete overview of the distribution of all species during cycling, we present a comparison between the output of a physicochemical model [4] with experimental data obtained from UV-Vis spectroscopy [1], X-ray diffraction [2] and electrochemical impedance spectroscopy [3]. The model affirms that the highest concentration of polysulfide is observed when all sulfur has been dissolved. In the tested cells, this occurs at around 37% DOD (450 Ah∙kgS−1). A significant concentration of polysulfides is confirmed at the end of discharge which is of significant importance for improving the cycling stability of lithium-sulfur cells.
elib-URL des Eintrags: | https://elib.dlr.de/90594/ | ||||||||||||||||||||||||
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Dokumentart: | Konferenzbeitrag (Poster) | ||||||||||||||||||||||||
Titel: | Experimental and Theoretical Analysis of Products and Reaction Intermediates of Discharge Process in Lithium-Sulfur Batteries | ||||||||||||||||||||||||
Autoren: |
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Datum: | 3 September 2014 | ||||||||||||||||||||||||
Referierte Publikation: | Nein | ||||||||||||||||||||||||
Open Access: | Ja | ||||||||||||||||||||||||
Gold Open Access: | Nein | ||||||||||||||||||||||||
In SCOPUS: | Nein | ||||||||||||||||||||||||
In ISI Web of Science: | Nein | ||||||||||||||||||||||||
Status: | veröffentlicht | ||||||||||||||||||||||||
Stichwörter: | Lithiu sulfur, Uv-Vis, Batterien, Characterization, simulations | ||||||||||||||||||||||||
Veranstaltungstitel: | 65th Annual Meeting of the International Society of Electrochemistry | ||||||||||||||||||||||||
Veranstaltungsort: | Lausanne, Schweiz | ||||||||||||||||||||||||
Veranstaltungsart: | internationale Konferenz | ||||||||||||||||||||||||
Veranstaltungsbeginn: | 31 August 2014 | ||||||||||||||||||||||||
Veranstaltungsende: | 5 September 2014 | ||||||||||||||||||||||||
Veranstalter : | ISE | ||||||||||||||||||||||||
HGF - Forschungsbereich: | Energie | ||||||||||||||||||||||||
HGF - Programm: | Rationelle Energieumwandlung und Nutzung (alt) | ||||||||||||||||||||||||
HGF - Programmthema: | Brennstoffzelle (alt) | ||||||||||||||||||||||||
DLR - Schwerpunkt: | Energie | ||||||||||||||||||||||||
DLR - Forschungsgebiet: | E EV - Energieverfahrenstechnik | ||||||||||||||||||||||||
DLR - Teilgebiet (Projekt, Vorhaben): | E - Elektrochemische Prozesse (alt) | ||||||||||||||||||||||||
Standort: | Stuttgart | ||||||||||||||||||||||||
Institute & Einrichtungen: | Institut für Technische Thermodynamik > Elektrochemische Energietechnik | ||||||||||||||||||||||||
Hinterlegt von: | Cañas, Natalia Andrea | ||||||||||||||||||||||||
Hinterlegt am: | 17 Dez 2014 17:35 | ||||||||||||||||||||||||
Letzte Änderung: | 24 Apr 2024 19:56 |
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