Complex atomic dynamics in a deep-eutectic binary metallic melt

Kurzfassung

Quasielastic neutron scattering (QENS) was used to explore relaxation processes in a deep-eutectic Ce80Ni20 melt over a temperature range of 750 K, i.e., from 775 K to 1525 K. At low temperatures (T = 890 K), the self-correlation function shows a fast b-relaxation process. The a-relaxation process displays stretching of the self-correlation and obeys a time-temperature superposition principle that extends over the entire measured temperature range. Even though the decay of the self-correlation functions of the Ce80Ni20 melt exhibit that of glass-forming melts, the temperature dependence of self-diffusivity displays an Arrhenius behavior, as observed for many simple, non-glass forming liquids.