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Modeling and Simulation of Metal-Sulfur Battery with Sulfurized Polyacrylonitrile (SPAN) Cathodes

Simanjuntak, Esther Kezia und Danner, Timo und Wang, Peiwen und Buchmeiser, Michael, R. und Latz, Arnulf (2022) Modeling and Simulation of Metal-Sulfur Battery with Sulfurized Polyacrylonitrile (SPAN) Cathodes. 32nd Topical Meeting of the International Society of Electrochemistry, 2022-06-19 - 2022-06-22, Stockholm, Schweden.

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Kurzfassung

The increasing demand for rechargeable and high-energy density batteries for portable devices, electric vehicles, and large-scale stationary storage systems has driven the intensive research to find more sustainable and economical materials. Lithium–sulfur (Li–S) batteries have been considered as a promising material for next-generation batteries with very high theoretical capacity (2,062 mAh/cm3). However, repeated plating and stripping of Li can lead to the growth of dendrites that potentially cause short circuits and battery failure. In recent years, magnesium (Mg) was proposed as anode material for Metal-Sulfur (Me-S) batteries due to its reduced tendency to dendrite formation and high volumetric capacity (3,837 mAh/cm3) [1]. Unfortunately, similarly to Li-S batteries, Mg-S batteries show a low coulombic efficiency and fast self-discharge due to the polysulfide shuttleSeveral mitigation strategies to reduce the polysulfide shuttle effect, have been developed for Li-S batteries and some of these concepts have been also transferred to Mg-S batteries [2]. One of the promising approaches is to covalently bind the sulfur to a polymer backbone. Long cycle life and high specific capacities have been demonstrated for sulfurated poly(acrylonitrile) (SPAN) cathodes in lithium-based batteries and, more recently, the proof-of-concept was also shown for Mg-SPAN batteries [3,4]. In our contribution, we present a novel continuum model for SPAN electrodes and demonstrate its application to Me-SPAN batteries. Within our simulation framework we include both red/ox reactions of sulfur covalently bound to the polymeric backbone of SPAN and transport as well as electrochemical reactions of the polysulfides in solution. Model parameters are extracted from structural and electrochemical characterization of SPAN composite electrodes and we demonstrate that we were able to reproduce the measured discharge curves. Starting with this standard configuration we perform simulation studies to investigate the influence of electrode geometric parameters such as electrode thickness and tortuosity on Li-SPAN cell performance. Finally, we apply our model for the simulation of Mg-SPAN batteries with dual salt electrolyte and investigate the kinetic mechanism in this complex electrochemical system. In collaboration with our experimental partners, we aim on providing more insights into the degradation mechanisms and limiting factors for battery performance, which are able to guide new developments for Me-SPAN batteries.

elib-URL des Eintrags:https://elib.dlr.de/191433/
Dokumentart:Konferenzbeitrag (Poster)
Titel:Modeling and Simulation of Metal-Sulfur Battery with Sulfurized Polyacrylonitrile (SPAN) Cathodes
Autoren:
AutorenInstitution oder E-Mail-AdresseAutoren-ORCID-iDORCID Put Code
Simanjuntak, Esther KeziaEsther.Simanjuntak (at) dlr.deNICHT SPEZIFIZIERTNICHT SPEZIFIZIERT
Danner, TimoTimo.Danner (at) dlr.dehttps://orcid.org/0000-0003-2336-6059NICHT SPEZIFIZIERT
Wang, PeiwenInstitute of Polymer Chemistry, University of StuttgartNICHT SPEZIFIZIERTNICHT SPEZIFIZIERT
Buchmeiser, Michael, R.michael.buchmeiser (at) ipoc.uni-stuttgart.deNICHT SPEZIFIZIERTNICHT SPEZIFIZIERT
Latz, ArnulfArnulf.Latz (at) dlr.deNICHT SPEZIFIZIERTNICHT SPEZIFIZIERT
Datum:2022
Referierte Publikation:Ja
Open Access:Ja
Gold Open Access:Nein
In SCOPUS:Nein
In ISI Web of Science:Nein
Status:veröffentlicht
Stichwörter:Continuum modelling, kinetics, rechargeable Metal-Sulfurized Polyacrylonitrile (SPAN) bat-teries
Veranstaltungstitel:32nd Topical Meeting of the International Society of Electrochemistry
Veranstaltungsort:Stockholm, Schweden
Veranstaltungsart:internationale Konferenz
Veranstaltungsbeginn:19 Juni 2022
Veranstaltungsende:22 Juni 2022
HGF - Forschungsbereich:Energie
HGF - Programm:Materialien und Technologien für die Energiewende
HGF - Programmthema:Elektrochemische Energiespeicherung
DLR - Schwerpunkt:Energie
DLR - Forschungsgebiet:E SP - Energiespeicher
DLR - Teilgebiet (Projekt, Vorhaben):E - Elektrochemische Speicher
Standort: Ulm
Institute & Einrichtungen:Institut für Technische Thermodynamik > Computergestützte Elektrochemie
Hinterlegt von: Simanjuntak, Esther Kezia
Hinterlegt am:12 Dez 2022 18:58
Letzte Änderung:12 Jun 2024 15:17

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