Nechache, Aziz und Han, Feng und Semerad, Robert und Schiller, Günter und Costa, Rémi (2017) Evaluation of Performance and Degradation Profiles of a Metal Supported Solid Oxide Fuel Cell Under Electrolysis Operation. ECS Transactions, 78 (1), Seiten 3039-3047. Electrochemical Society, Inc.. doi: 10.1149/07801.3039. ISSN 1938-5862.
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Kurzfassung
In the context of energy transition, the use of renewable energies through the conversion of different resources with promising technologies into storable energy carriers is of eminent importance for a sustainable energy supply. Hydrogen production from steam using solid oxide electrolysis cells (SOEC) is part of this so called “energy mix”. Recently, promising progress appeared from the investigation of metal supports in the solid oxide cell architecture. Metal-supported solid oxide fuel cells (MS-SOFCs) show not only good mechanical strength, relatively low operating temperature (500-750°C) and improved sealing capability but also low materials cost and tolerance towards rapid thermal cycling and redox cycling (1-3). In the present study, a MS-SOFC was tested under electrolysis conditions. The cell consisted of Ni-catalyst loaded La0.1Sr0.9TiO3-α/gadolinium-doped ceria (Ni-LST/GDC) as fuel electrode, gadolinium-doped ceria / yttrium-stabilized zirconia (GDC/YSZ) as electrolyte and La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF) as O2 electrode. The cell was first tested in fuel cell mode under different gas compositions. Subsequently, a first evaluation of the cell performance profile in electrolysis mode was performed. Thus, a series of current-voltage curves as well as impedance diagrams (under OCV and under load) was recorded. Furthermore, degradation under electrolysis operation was also investigated based on the evolution of the cell voltage against time.
elib-URL des Eintrags: | https://elib.dlr.de/115420/ | ||||||||||||||||||||||||
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Dokumentart: | Zeitschriftenbeitrag | ||||||||||||||||||||||||
Titel: | Evaluation of Performance and Degradation Profiles of a Metal Supported Solid Oxide Fuel Cell Under Electrolysis Operation | ||||||||||||||||||||||||
Autoren: |
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Datum: | 2017 | ||||||||||||||||||||||||
Erschienen in: | ECS Transactions | ||||||||||||||||||||||||
Referierte Publikation: | Ja | ||||||||||||||||||||||||
Open Access: | Ja | ||||||||||||||||||||||||
Gold Open Access: | Nein | ||||||||||||||||||||||||
In SCOPUS: | Nein | ||||||||||||||||||||||||
In ISI Web of Science: | Nein | ||||||||||||||||||||||||
Band: | 78 | ||||||||||||||||||||||||
DOI: | 10.1149/07801.3039 | ||||||||||||||||||||||||
Seitenbereich: | Seiten 3039-3047 | ||||||||||||||||||||||||
Herausgeber: |
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Verlag: | Electrochemical Society, Inc. | ||||||||||||||||||||||||
ISSN: | 1938-5862 | ||||||||||||||||||||||||
Status: | veröffentlicht | ||||||||||||||||||||||||
Stichwörter: | Metal-supported SOFC, electrolysis operation, Ni-LST/GDC fuel electrode, impedance spectroscopy, degradation | ||||||||||||||||||||||||
HGF - Forschungsbereich: | Energie | ||||||||||||||||||||||||
HGF - Programm: | Speicher und vernetzte Infrastrukturen | ||||||||||||||||||||||||
HGF - Programmthema: | Elektrolyse und Wasserstoff | ||||||||||||||||||||||||
DLR - Schwerpunkt: | Energie | ||||||||||||||||||||||||
DLR - Forschungsgebiet: | E SP - Energiespeicher | ||||||||||||||||||||||||
DLR - Teilgebiet (Projekt, Vorhaben): | E - Elektrochemische Prozesse (Elektrolyse) (alt) | ||||||||||||||||||||||||
Standort: | Stuttgart | ||||||||||||||||||||||||
Institute & Einrichtungen: | Institut für Technische Thermodynamik > Elektrochemische Energietechnik | ||||||||||||||||||||||||
Hinterlegt von: | Schiller, Dr.rer.nat. Günter | ||||||||||||||||||||||||
Hinterlegt am: | 01 Dez 2017 14:56 | ||||||||||||||||||||||||
Letzte Änderung: | 31 Okt 2020 04:35 |
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