High resolution ro-vibrational analysis of the nu2 spectral region of chlorine nitrate
Lafferty, W.J. and Flaud, Jean Marie and Birk, Manfred and Wagner, Georg and Orphal, J. (2005) High resolution ro-vibrational analysis of the nu2 spectral region of chlorine nitrate. Molecular Physics, 103 (4), .
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A thorough ro-vibrational analysis of the hybrid (A- and B-type) nu_2 bands of 35ClONO2 and 37ClONO2 has been carried out using a high-resolution (0.0009 cm-1) Fourier transform spectrum recorded at 190 K. Unlike previously studied infrared bands, weak PP- and RR-branch series were observed. From these transitions, very high Ka upper-state energy levels were obtained which permitted a satisfactory modelling of the strong Q-branch at about 1292.5 cm-1. Accurate upper-state constants have been derived for all bands including the following band centres: nu_0 (nu_2) 1292.83690(40) cm-1 and nu_0 (nu_2) 1293.20801(50) cm-1 for the 35Cl and 37Cl isotopomers respectively.
|Title:||High resolution ro-vibrational analysis of the nu2 spectral region of chlorine nitrate|
|Journal or Publication Title:||Molecular Physics|
|In ISI Web of Science:||Yes|
|Keywords:||Chlorine nitrate; Infrared; high resolution; Spectroscopic database; Remote sensing;|
|HGF - Research field:||Aeronautics, Space and Transport|
|HGF - Program:||Space|
|HGF - Program Themes:||W EO - Erdbeobachtung|
|DLR - Research area:||Space|
|DLR - Program:||W EO - Erdbeobachtung|
|DLR - Research theme (Project):||UNSPECIFIED|
|Institutes and Institutions:||Remote Sensing Technology Institute|
|Deposited By:||Cornelia Roehl|
|Deposited On:||08 May 2006|
|Last Modified:||06 Jan 2010 22:39|
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