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Quantitative Analysis of the Products of the ClO Self Reaction at Low Temperature

Birk, Manfred and Friedl, R. R. and Cohen, E. A. (1990) Quantitative Analysis of the Products of the ClO Self Reaction at Low Temperature. In: Proceedings of the First European Workshop on Polar Stratospheric Ozone Research. First European Workshop on Polar Stratospheric Ozone Research, Schliersee, 1990.

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Abstract

The relative intensities of individual rotational absorption lines of ClOCl, ClO, ClOOCl and OClO have been measured in the submillimeter wave region around 400 GHz. Stark measurements were taken to estimate the dipole moments of ClOCl and ClOOCl thus allowing calculation of relative concentrations. At low initial ClO concentrations ClOOCl product accounts entirely for the reacted ClO within experimental uncertainty. Consequently, ClOOCl is the major product of the ClO self reaction at polar stratospheric conditions.

Document Type:Conference or Workshop Item (Paper)
Additional Information: LIDO-Berichtsjahr=1990,
Title:Quantitative Analysis of the Products of the ClO Self Reaction at Low Temperature
Authors:
AuthorsInstitution or Email of Authors
Birk, ManfredUNSPECIFIED
Friedl, R. R.Jet Propulsion Laboratory, Pasadena, USA
Cohen, E. A.UNSPECIFIED
Date:1990
Journal or Publication Title:Proceedings of the First European Workshop on Polar Stratospheric Ozone Research
Status:Published
Keywords:Atmospheric chemistry, Stratosphere, Ozone Hole, Spectroscopy, Photoc hemistry
Event Title:First European Workshop on Polar Stratospheric Ozone Research, Schliersee, 1990
HGF - Research field:Aeronautics, Space and Transport (old)
HGF - Program:other
HGF - Program Themes:other
DLR - Research area:Space
DLR - Program:no assignment
DLR - Research theme (Project):UNSPECIFIED
Location: Oberpfaffenhofen
Institutes and Institutions:Institut für Optoelektronik
Deposited By: elib DLR-Beauftragter
Deposited On:29 May 2006
Last Modified:27 Apr 2009 09:32

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